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Department of Chemistry and Materials Science

Physical Chemistry and Electrochemistry

The group has lately studied externally triggered drug delivery, electrochemical energy storage, electrodialysis and electrochemistry in two phase (oil-water) systems.
CV duck
Voltammetric duck

Research projects:

Our research projects include:

  1. All Copper redox flow battery (CuRen-M)
  2. Electrodialysis with bipolar membranes (CREDIT). Finished in the end of 2023. 
  3. Electrochemistry at the liquid-liquid interface (ITIES). No more active.
All Copper Redox Flow Battery
All Copper Redox Flow Battery

All Copper redox flow battery (CuRen)

The problem of wind and solar energy production is that it is intermittent, not always meeting the need of electric power. Therefore, storing renewable energy to level consumption peaks and lows becomes very important. Large amounts of electric energy are mainly stored in pumped hydropower. From electrochemical methods a flow battery is practically the only one which is easily scalable to the MWh range. The principle of operation of a redox flow battery is presented in Figure 2, also showing the electrode reactions of the all-copper RFB. The capacity of a RFB can in principle be increased without limits by increasing the volume of the electrolyte tanks.

The vanadium RFB is already commercialized but the limited availability of vanadium prevents its use on the global scale. Hence, the focus of our research is to develop a RFB that is based on copper electrochemistry. The study has been funded by EU and

Current project is found .

Principle of the process

Electrodialysis with bipolar membranes (CREDIT)

In hydrometallurgy, leaching is usually done with sulfuric acid that is neutralized by alkaline, resulting significant amounts of aqueous sulfate salt as waste. The amount of sodium sulfate waste in mines and mineral processes will grow considerably in the future as the need for battery chemicals for energy storage and electric vehicles are continuously increasing. Its low value with high processing costs and the savings in chemical costs are critical issues for its recycling. We are developing a novel technology concept for water treatment and chemical recovery of highly concentrated low-value sulfate waste from a battery chemical plant.

The main aim of the project CREDIT is to scale-­up the bipolar electrodialysis (BPED) technology for recycling sodium sulfate in hydrometallurgical processes by converting it to sodium hydroxide and sulfuric acid. We will also provide an economically feasible bipolar membrane-based technology which will reduce environmental discharges. Furthermore, we shall focus on also most suitable pretreatment and post-treatment technologies. The project is financed program; the other participants are , , , and .

ET at ITIES

Electrochemistry at the liquid-liquid interface (ITIES)

During the past 30 years, we have studied the electrochemistry of liquid-liquid interfaces, which is quite an original area of research in the field of electrochemistry. Now the research is focused to the metal extraction and reduction boosted with Galvani potential difference across the interface. Experiments are done with the scanning electrochemical microscope (SECM), fixing the Galvani potential difference between the phases via electrolytes distribution (LiTB and BATB).

Funding:

SECM at ITIES
Experimental setup for SECM measurements @ ITIES. MIBK = methyl isobutyl ketone.
Our textbooks

Teaching:

  • Electrochemistry
  • Transport processes

Research group members:

Latest publications

Mirko D’Adamo, Wouter Badenhorst, Lasse Murtomäki, Paula Cordoba, Mohamed Derbeli, Jose A. Saez-Zamora, Lluís Trilla 2025 Energies

Simona de Zio, Giampaolo Lacarbonara, Wouter Badenhorst, Marco Malferrari, Rossella Petruzzelli, Lasse Murtomäki, Catia Arbizzani, Stefania Rapino 2025 Electrochimica Acta

Wouter Badenhorst, Jose Antonio Manzanares, Lasse Murtomäki 2024 Langmuir

Wouter Badenhorst, Christian M. Jensen, Uffe Jacobsen, Zahra Estafani, Lasse Murtomäki 2023 Batteries

Tommi Ahonen, Moritz Rosenthal, Lasse Murtomäki 2023 Chemical Engineering Journal Advances

Eemi Nieminen 2023

Laura Sanz Rubio, Wouter Badenhorst, Gianpaolo Lacarbonara, Luigi Faggiano, David Lloyd, Pertti Kauranen, Catia Arbizzani, Lasse Murtomäki 2023 Flow Batteries

Wouter Dirk Badenhorst, Laura Sanz, Catia Arbizzani, Lasse Murtomäki 2022 Energy Reports

Luigi Faggiano, Gianluca Lacarbonara, Wouter Badenhorst, Lasse Murtomäki, Laura Sanz Rubio, Catia Arbizzani 2022 Journal of Power Sources

Kuldeep Kuldeep, José Antonio Manzanares, Pertti Kauranen, Seyedabolfazl Mousavihashemi, Lasse Murtomäki 2022 ChemElectroChem
More information on our research in the Aalto research portal.
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